Studies on the Chemistry of Manganese Tricarbonyl Cations of Phenol and Cresols

Studies on the Chemistry of Manganese Tricarbonyl Cations of Phenol and Cresols

Treatment of (arene)tricarbonylmanganese cations (arene = phenol, cresol) with nucleophiles affords η5-cyclohexadienyl complexes that can be demetalated to give ortho-substituted phenols. Acylation of the phenolic oxygen in the η5-cyclohexadienyl complexes obtained from phenol, followed by treatment...

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Veröffentlicht in:Organometallics 2002-08, Vol.21 (16), p.3417-3425
Hauptverfasser: Seo, Hwimin, Lee, Si-Geun, Shin, Dong Mok, Hong, Bog Ki, Hwang, Sungu, Chung, Doo Soo, Chung, Young Keun
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container_end_page 3425
container_issue 16
container_start_page 3417
container_title Organometallics
container_volume 21
creator Seo, Hwimin
Lee, Si-Geun
Shin, Dong Mok
Hong, Bog Ki
Hwang, Sungu
Chung, Doo Soo
Chung, Young Keun
description Treatment of (arene)tricarbonylmanganese cations (arene = phenol, cresol) with nucleophiles affords η5-cyclohexadienyl complexes that can be demetalated to give ortho-substituted phenols. Acylation of the phenolic oxygen in the η5-cyclohexadienyl complexes obtained from phenol, followed by treatment with acid, gives manganese tricarbonyl cations with coordinated monosubstituted arenes. Reaction of η5-cyclohexadienyl complexes derived from ortho- and para-cresol with acid gives meta-substituted toluene manganese tricarbonyl cations, and those derived from meta-cresol give ortho- and/or para-substituted toluene manganese complexes depending upon the nucleophiles.
doi_str_mv 10.1021/om020194m
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