Rhodium Phosphines Partnered with the Carborane Monoanions [CB11H6Y6]- (Y = H, Br). Synthesis and Evaluation as Alkene Hydrogenation Catalysts

Addition of Ag[closo-CB11H12] to [(PPh3)2RhCl]2 affords the new exopolyhedrally coordinated complex [(PPh3)2Rh(closo-CB11H12)] (1), which has been characterized by multinuclear NMR spectroscopy and X-ray crystallography. Using the less nucleophilic [closo-CB11H6Br6]- anion afforded the arene-bridged...

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Veröffentlicht in:	Organometallics 2002-07, Vol.21 (14), p.2856-2865
Hauptverfasser:	Rifat, Adem, Patmore, Nathan J, Mahon, Mary F, Weller, Andrew S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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