Configurational Stability of [Di(amino)silyl]lithiums Having Cyclic Structures

Cyclic diamino-substituted silyllithiums, [(N,N ‘-diisopropyldiamino)silyl]lithiums, were prepared by the reaction of lithium with the corresponding chlorosilanes. The methyls in the isopropyl groups are diastereotopic and anisochronous at room temperature in THF and in diglyme. Variable-temperature...

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Veröffentlicht in:	Organometallics 2002-03, Vol.21 (6), p.1319-1321
Hauptverfasser:	Kawachi, Atsushi, Maeda, Hirofumi, Tamao, Kohei
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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