One-Step Synthesis of Fluorenyl-Substituted Chlorosilanes:  Friedel−Crafts Type Cycloalkylation of Biphenyl with (Dichloroalkyl)silane

Friedel−Crafts alkylation reactions of biphenyl with (dichloroalkyl)chlorosilanes [Cl3 - m Me m Si(C n H2 n - 1Cl2), m = 0−2, n = 1−3] at temperatures ranging from 120 to 160 °C in the presence of a Lewis acid catalyst gave cyclized products, fluorenyl-substituted chlorosilanes, in 47−94% yields. In...

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Veröffentlicht in:Organometallics 2001-12, Vol.20 (26), p.5586-5590
Hauptverfasser: Song, Young-Sang, Kong, Seong Deok, Khan, Shah Alam, Yoo, Bok Ryul, Jung, Il Nam
Format: Artikel
Sprache:eng
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