Dissociative CO Photosubstitution in M(CO)4(1,4-diazabutadiene) Complexes (M = W, Mo) by an Olefin Affording Novel f ac-M(CO)3(1,4-diazabutadiene)(η2-olefin) Derivatives

Photolysis of M(CO)4(iprop-dab) (1, M = W; 2, M = Mo; iprop-dab = 1,4-diisopropyl-1,4-diazabuta-1,3-diene) in the presence of (E)-cyclooctene (eco) afforded high yields of the unprecedented olefin-substituted derivatives fac-M(CO)3(iprop-dab)(η2-eco) (3, M = W, 93%; 4, M = Mo, 84%), which were compr...

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Veröffentlicht in:	Organometallics 2001-11, Vol.20 (23), p.4775-4792
Hauptverfasser:	Grevels, Friedrich-Wilhelm, Kerpen, Klaus, Klotzbücher, Werner E, Schaffner, Kurt, Goddard, Richard, Weimann, Bruno, Kayran, Ceyhan, Özkar, Saim
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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