Intramolecular carbon-hydrogen bond activation of benzyl ligands by metalated cyclopentadienyl derivatives of permethylhafnocene. Molecular structure of (.eta.5-C5Me5)(.eta.5,.eta.1-C5Me4CH2)HfCH2C6H5 and the mechanism of rearrangement to its hafnabenzocyclobutene tautomer [cyclic] (.eta.5-C5Me5)2Hf(o-CH2C6H4)

Intramolecular carbon-hydrogen bond activation of benzyl ligands by metalated cyclopentadienyl derivatives of permethylhafnocene. Molecular structure of (.eta.5-C5Me5)(.eta.5,.eta.1-C5Me4CH2)HfCH2C6H5 and the mechanism of rearrangement to its hafnabenzocyclobutene tautomer [cyclic] (.eta.5-C5Me5)2Hf(o-CH2C6H4)

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Veröffentlicht in:Organometallics 1987-06, Vol.6 (6), p.1219-1226
Hauptverfasser: Bulls, A. Ray, Schaefer, William P, Serfas, Michael, Bercaw, John E
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container_title Organometallics
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title Intramolecular carbon-hydrogen bond activation of benzyl ligands by metalated cyclopentadienyl derivatives of permethylhafnocene. Molecular structure of (.eta.5-C5Me5)(.eta.5,.eta.1-C5Me4CH2)HfCH2C6H5 and the mechanism of rearrangement to its hafnabenzocyclobutene tautomer [cyclic] (.eta.5-C5Me5)2Hf(o-CH2C6H4)
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