Coordination Chemistry of Cyclopentadienyl Ester-Disubstituted Ligands. Synthesis and Solid State Structures of [Na([18]-crown-6)][C5H3(CO2Et)2-1,2] and [Mn{C5H3(CO2Ph)2-1,2}(CO)3]

The disubstituted alkyl- and aryloxycarbonylcyclopentadienides of sodium Na[C5H3(CO2R)2-1,2] [R = Me (3a), Et (3b), Ph (3c)] are obtained in a two-step synthesis. The known Na[C5H4(CO2R)] [R = Me (1a), Et (2b)] and the hitherto unknown Na[C5H4(CO2Ph)] (1c), prepared from NaCp and dialkyl- or dipheny...

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Veröffentlicht in:	Organometallics 2001-01, Vol.20 (2), p.282-288
Hauptverfasser:	Busetto, Luigi, Cassani, M. Cristina, Zanotti, Valerio, Albano, Vincenzo G, Sabatino, Piera
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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