Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts

({eta}{sup 5}-5,6-X{sub 2}C{sub 9}H{sub 5}){sub 2}ZrCl{sub 2} catalysts (4a, X = H; 4b, X = CH{sub 3}; 4d, X = OCH{sub 3}; 4e, X = Cl) were investigated as catalysts for the polymerization of ethylene. In addition, polymerization of propylene and ethylene was studied by using corresponding racemic,...

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Veröffentlicht in:	Organometallics 1992-06, Vol.11 (6), p.2115-2122
Hauptverfasser:	Lee, Ik Mo, Gauthier, William J, Ball, JoAnne M, Iyengar, Bhagavathi, Collins, Scott
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY Applied sciences CATALYTIC EFFECTS ELECTRONIC STRUCTURE ETHYLENE Exact sciences and technology Organic polymers ORGANOMETALLIC COMPOUNDS Physicochemistry of polymers POLYMERIZATION Preparation, kinetics, thermodynamics, mechanism and catalysts PROPYLENE ZIEGLER CATALYST ZIRCONIUM COMPLEXES
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