Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts
({eta}{sup 5}-5,6-X{sub 2}C{sub 9}H{sub 5}){sub 2}ZrCl{sub 2} catalysts (4a, X = H; 4b, X = CH{sub 3}; 4d, X = OCH{sub 3}; 4e, X = Cl) were investigated as catalysts for the polymerization of ethylene. In addition, polymerization of propylene and ethylene was studied by using corresponding racemic,...
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| Veröffentlicht in: | Organometallics 1992-06, Vol.11 (6), p.2115-2122 |
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| container_issue | 6 |
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| container_title | Organometallics |
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| creator | Lee, Ik Mo Gauthier, William J Ball, JoAnne M Iyengar, Bhagavathi Collins, Scott |
| description | ({eta}{sup 5}-5,6-X{sub 2}C{sub 9}H{sub 5}){sub 2}ZrCl{sub 2} catalysts (4a, X = H; 4b, X = CH{sub 3}; 4d, X = OCH{sub 3}; 4e, X = Cl) were investigated as catalysts for the polymerization of ethylene. In addition, polymerization of propylene and ethylene was studied by using corresponding racemic, ethylene-bridged analogues (5a, X = H; 5b, X = CH{sub 3}; 5d, X = OCH{sub 3}). Both the bridged and non-bridged catalysts were effective as catalysts for both ethylene and propylene polymerization, but the molecular weights were generally lower with the ethylene-bridged catalyst. 19 refs., 3 tabs. |
| doi_str_mv | 10.1021/om00042a027 |
| format | Article |
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In addition, polymerization of propylene and ethylene was studied by using corresponding racemic, ethylene-bridged analogues (5a, X = H; 5b, X = CH{sub 3}; 5d, X = OCH{sub 3}). Both the bridged and non-bridged catalysts were effective as catalysts for both ethylene and propylene polymerization, but the molecular weights were generally lower with the ethylene-bridged catalyst. 19 refs., 3 tabs.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om00042a027</identifier><identifier>CODEN: ORGND7</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>40 CHEMISTRY ; Applied sciences ; CATALYTIC EFFECTS ; ELECTRONIC STRUCTURE ; ETHYLENE ; Exact sciences and technology ; Organic polymers ; ORGANOMETALLIC COMPOUNDS ; Physicochemistry of polymers ; POLYMERIZATION ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; PROPYLENE ; ZIEGLER CATALYST ; ZIRCONIUM COMPLEXES</subject><ispartof>Organometallics, 1992-06, Vol.11 (6), p.2115-2122</ispartof><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a358t-bc5e21d5a9d070ddbe664537f48b62f6dbfde0643c347f8f0f35cedf06d243c03</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om00042a027$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om00042a027$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5443714$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/458729$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Lee, Ik Mo</creatorcontrib><creatorcontrib>Gauthier, William J</creatorcontrib><creatorcontrib>Ball, JoAnne M</creatorcontrib><creatorcontrib>Iyengar, Bhagavathi</creatorcontrib><creatorcontrib>Collins, Scott</creatorcontrib><title>Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>({eta}{sup 5}-5,6-X{sub 2}C{sub 9}H{sub 5}){sub 2}ZrCl{sub 2} catalysts (4a, X = H; 4b, X = CH{sub 3}; 4d, X = OCH{sub 3}; 4e, X = Cl) were investigated as catalysts for the polymerization of ethylene. In addition, polymerization of propylene and ethylene was studied by using corresponding racemic, ethylene-bridged analogues (5a, X = H; 5b, X = CH{sub 3}; 5d, X = OCH{sub 3}). Both the bridged and non-bridged catalysts were effective as catalysts for both ethylene and propylene polymerization, but the molecular weights were generally lower with the ethylene-bridged catalyst. 19 refs., 3 tabs.</description><subject>40 CHEMISTRY</subject><subject>Applied sciences</subject><subject>CATALYTIC EFFECTS</subject><subject>ELECTRONIC STRUCTURE</subject><subject>ETHYLENE</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>ORGANOMETALLIC COMPOUNDS</subject><subject>Physicochemistry of polymers</subject><subject>POLYMERIZATION</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>PROPYLENE</subject><subject>ZIEGLER CATALYST</subject><subject>ZIRCONIUM COMPLEXES</subject><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNptkF1rFTEQhoMoeKxe-QdWELyQbbP53F5KrbZwqAVrKb0J2WTSpuYkS5IDPf56c9hSvPBqPt5nhpkXofcDPhwwGY7SBmPMiMZEvkCrgRPcC8yGl2jVOqKXlNLX6E0pDw0TkpIVmk8DmJpT9KYD51peuuS6Ww93AXJ_oWvV3ZzCbgPZ_9HVp7jX55zmXYAInY62g3q_FNvi411XUthOAboNVB1CMnvF6JbvSi1v0SunQ4F3T_EA_fp2enVy1q9_fD8_-bLuNeVj7SfDgQyW62OLJbZ2AiEYp9KxcRLECTs5C1gwaiiTbnTYUW7AOiwsaU1MD9CHZW8q1atifAVzb1KM7UXF-CjJcWM-L4zJqZQMTs3Zb3TeqQGrvaHqH0Mb_XGhZ12MDi7raHx5HuGMUTmwhvUL5kuFx2dZ59-qWS65urr8qb5ejmc31-tbtT_i08JrU9RD2ubYbPnvAX8B3uaT5w</recordid><startdate>19920601</startdate><enddate>19920601</enddate><creator>Lee, Ik Mo</creator><creator>Gauthier, William J</creator><creator>Ball, JoAnne M</creator><creator>Iyengar, Bhagavathi</creator><creator>Collins, Scott</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19920601</creationdate><title>Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts</title><author>Lee, Ik Mo ; Gauthier, William J ; Ball, JoAnne M ; Iyengar, Bhagavathi ; Collins, Scott</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a358t-bc5e21d5a9d070ddbe664537f48b62f6dbfde0643c347f8f0f35cedf06d243c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>40 CHEMISTRY</topic><topic>Applied sciences</topic><topic>CATALYTIC EFFECTS</topic><topic>ELECTRONIC STRUCTURE</topic><topic>ETHYLENE</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>ORGANOMETALLIC COMPOUNDS</topic><topic>Physicochemistry of polymers</topic><topic>POLYMERIZATION</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>PROPYLENE</topic><topic>ZIEGLER CATALYST</topic><topic>ZIRCONIUM COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Ik Mo</creatorcontrib><creatorcontrib>Gauthier, William J</creatorcontrib><creatorcontrib>Ball, JoAnne M</creatorcontrib><creatorcontrib>Iyengar, Bhagavathi</creatorcontrib><creatorcontrib>Collins, Scott</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Ik Mo</au><au>Gauthier, William J</au><au>Ball, JoAnne M</au><au>Iyengar, Bhagavathi</au><au>Collins, Scott</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1992-06-01</date><risdate>1992</risdate><volume>11</volume><issue>6</issue><spage>2115</spage><epage>2122</epage><pages>2115-2122</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><coden>ORGND7</coden><abstract>({eta}{sup 5}-5,6-X{sub 2}C{sub 9}H{sub 5}){sub 2}ZrCl{sub 2} catalysts (4a, X = H; 4b, X = CH{sub 3}; 4d, X = OCH{sub 3}; 4e, X = Cl) were investigated as catalysts for the polymerization of ethylene. In addition, polymerization of propylene and ethylene was studied by using corresponding racemic, ethylene-bridged analogues (5a, X = H; 5b, X = CH{sub 3}; 5d, X = OCH{sub 3}). Both the bridged and non-bridged catalysts were effective as catalysts for both ethylene and propylene polymerization, but the molecular weights were generally lower with the ethylene-bridged catalyst. 19 refs., 3 tabs.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/om00042a027</doi><tpages>8</tpages></addata></record> |
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| source | ACS Publications |
| subjects | 40 CHEMISTRY Applied sciences CATALYTIC EFFECTS ELECTRONIC STRUCTURE ETHYLENE Exact sciences and technology Organic polymers ORGANOMETALLIC COMPOUNDS Physicochemistry of polymers POLYMERIZATION Preparation, kinetics, thermodynamics, mechanism and catalysts PROPYLENE ZIEGLER CATALYST ZIRCONIUM COMPLEXES |
| title | Electronic effects of Ziegler-Natta polymerization of propylene and ethylene using soluble metallocene catalysts |
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