Reactivity of CpRh 16e Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolato Ligand. Intermediates in the Catalyzed Trimerization of Methyl Acetylene Carboxylate and Phenylacetylene

Reactions of the 16-electron (16e) half-sandwich complexes Cp*Rh[E2C2(B10H10)] [E = S (1S), Se (1Se)] with methyl acetylene carboxylate and phenylacetylene were studied in order to obtain information on both the primary addition products and the potential catalyzed oligomerization of the alkynes as...

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Veröffentlicht in:	Organometallics 2000-10, Vol.19 (21), p.4289-4294
Hauptverfasser:	Herberhold, Max, Yan, Hong, Milius, Wolfgang, Wrackmeyer, Bernd
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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