Synthesis and Characterization of Derivatives of a Hydroxymethyl Ruthenium Complex

Synthesis and Characterization of Derivatives of a Hydroxymethyl Ruthenium Complex

Reaction of cis-Ru(bpy)2(CO)CH2OH+PF6 - (1, bpy = 2,2‘-bipyridine) with acetic anhydride yields the corresponding acetoxymethyl derivative 2. However, reaction of 1 with a large excess of acetic acid in acetonitrile yields compound 3, containing an acetamidomethyl ligand instead of the acetoxymethyl...

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Veröffentlicht in:Organometallics 2000-10, Vol.19 (20), p.4179-4182
Hauptverfasser: Gibson, Dorothy H, Srinivas, Bhamidi, Niemann, Brian, Sleadd, Bradley A, Mashuta, Mark S, Vij, Ashwani, Gallucci, Judith C
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container_end_page 4182
container_issue 20
container_start_page 4179
container_title Organometallics
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creator Gibson, Dorothy H
Srinivas, Bhamidi
Niemann, Brian
Sleadd, Bradley A
Mashuta, Mark S
Vij, Ashwani
Gallucci, Judith C
description Reaction of cis-Ru(bpy)2(CO)CH2OH+PF6 - (1, bpy = 2,2‘-bipyridine) with acetic anhydride yields the corresponding acetoxymethyl derivative 2. However, reaction of 1 with a large excess of acetic acid in acetonitrile yields compound 3, containing an acetamidomethyl ligand instead of the acetoxymethyl group. Compounds 2 and 3 have been characterized by X-ray crystallography; in the crystalline state, 3 exists as a binuclear compound held together by hydrogen bonds to a single water molecule through the acetyl carbonyl groups.
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title Synthesis and Characterization of Derivatives of a Hydroxymethyl Ruthenium Complex
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