Nonenzymatic Kinetic Resolution of 1,2-Diols Catalyzed by an Organotin Compound

Nonenzymatic Kinetic Resolution of 1,2-Diols Catalyzed by an Organotin Compound

A new nonenzymatic kinetic resolution method of 1,2-diols 1 using chiral organotin catalyst A with benzoyl chloride was developed. A remarkable effect due to an inorganic base such as sodium carbonate and a small portion of water on the ee of the main products 2 was observed. The reaction showed hig...

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Veröffentlicht in:Organic letters 1999-10, Vol.1 (7), p.969-972
Hauptverfasser: Iwasaki, Fumiaki, Maki, Toshihide, Nakashima, Waka, Onomura, Osamu, Matsumura, Yoshihiro
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container_end_page 972
container_issue 7
container_start_page 969
container_title Organic letters
container_volume 1
creator Iwasaki, Fumiaki
Maki, Toshihide
Nakashima, Waka
Onomura, Osamu
Matsumura, Yoshihiro
description A new nonenzymatic kinetic resolution method of 1,2-diols 1 using chiral organotin catalyst A with benzoyl chloride was developed. A remarkable effect due to an inorganic base such as sodium carbonate and a small portion of water on the ee of the main products 2 was observed. The reaction showed high enantio- and chemoselectivities to 1,2-diols 1.
doi_str_mv 10.1021/ol9908373
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title Nonenzymatic Kinetic Resolution of 1,2-Diols Catalyzed by an Organotin Compound
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