C 3-Symmetric Cage-like Receptors: Chiral Discrimination of α-Chiral Amines in a Confined Space

C 3-Symmetric Cage-like Receptors: Chiral Discrimination of α-Chiral Amines in a Confined Space

Cage-like receptors that have internal binding sites and a C 3-symmetric chiral bias have been synthesized, and their chiral discrimination behavior toward α-chiral amines as their ammonium salts has been compared with that of their open structures.

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Veröffentlicht in:Organic letters 2010-10, Vol.12 (19), p.4228-4231
Hauptverfasser: Sambasivan, Sunderraman, Kim, Sung-Gon, Choi, Sun Mi, Rhee, Young Min, Ahn, Kyo Han
Format: Artikel
Sprache:eng
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Zusammenfassung:Cage-like receptors that have internal binding sites and a C 3-symmetric chiral bias have been synthesized, and their chiral discrimination behavior toward α-chiral amines as their ammonium salts has been compared with that of their open structures.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol1015527