Monolayer and Multilayer Films of [Mn12O12(O2CMe)16]

The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been re...

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Veröffentlicht in:Nano letters 2004-03, Vol.4 (3), p.399-402
Hauptverfasser: Steckel, Jonathan S, Persky, Nicole S, Martinez, Chelsea R, Barnes, Calvin L, Fry, Elizabeth A, Kulkarni, Jaideep, Burgess, James D, Pacheco, Rachel B, Stoll, Sarah L
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container_end_page 402
container_issue 3
container_start_page 399
container_title Nano letters
container_volume 4
creator Steckel, Jonathan S
Persky, Nicole S
Martinez, Chelsea R
Barnes, Calvin L
Fry, Elizabeth A
Kulkarni, Jaideep
Burgess, James D
Pacheco, Rachel B
Stoll, Sarah L
description The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been reported. Here we demonstrate a simple approach using functionalized self-assembled monolayers and short-chain polyelectrolytes to make monolayer and nanometer-scale multilayer films of Mn-12.
doi_str_mv 10.1021/nl0343553
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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of nanofabrication
Physics
Self-assembly
title Monolayer and Multilayer Films of [Mn12O12(O2CMe)16]
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