Monolayer and Multilayer Films of [Mn12O12(O2CMe)16]

The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been re...

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Veröffentlicht in:	Nano letters 2004-03, Vol.4 (3), p.399-402
Hauptverfasser:	Steckel, Jonathan S, Persky, Nicole S, Martinez, Chelsea R, Barnes, Calvin L, Fry, Elizabeth A, Kulkarni, Jaideep, Burgess, James D, Pacheco, Rachel B, Stoll, Sarah L
Format:	Artikel
Sprache:	eng
Schlagworte:	Cross-disciplinary physics: materials science rheology Exact sciences and technology Materials science Methods of nanofabrication Physics Self-assembly
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been reported. Here we demonstrate a simple approach using functionalized self-assembled monolayers and short-chain polyelectrolytes to make monolayer and nanometer-scale multilayer films of Mn-12.
ISSN:	1530-6984 1530-6992
DOI:	10.1021/nl0343553