Self-Organized Monolayer Films of Stimulus-Responsive Micelles

Self-Organized Monolayer Films of Stimulus-Responsive Micelles

Weakly charged micelles of poly(2-(dimethylamino)ethyl methacrylate) [10% quaternized]-block-poly(2-(diethylamino)ethyl methacrylate) (10qDMA-DEA) adsorb to form a highly ordered monolayer at the mica−solution interface at pH 8.9. Rinsing with solvent at pH 9 has little effect on the adsorbed layer....

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Veröffentlicht in:Nano letters 2002-11, Vol.2 (11), p.1307-1313
Hauptverfasser: Webber, Grant B, Wanless, Erica J, Bütün, Vural, Armes, Steven P, Biggs, Simon
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container_issue 11
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container_title Nano letters
container_volume 2
creator Webber, Grant B
Wanless, Erica J
Bütün, Vural
Armes, Steven P
Biggs, Simon
description Weakly charged micelles of poly(2-(dimethylamino)ethyl methacrylate) [10% quaternized]-block-poly(2-(diethylamino)ethyl methacrylate) (10qDMA-DEA) adsorb to form a highly ordered monolayer at the mica−solution interface at pH 8.9. Rinsing with solvent at pH 9 has little effect on the adsorbed layer. Reduction of the pH to 4 results in an irreversible swelling of the thin film, in contrast to a micelle-to-unimer transition seen for the diblock in bulk solution. The resilience of the adsorbed layer opens up potential nanotechnological applications.
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