Study of the Propagation Center in the Anionic Polymerization of (Meth)acrylic Monomers: NMR Study of Di-tert-butyl 2-Lithio-2,4,4‘-trimethylglutarate and Living Poly(tert-butyl methacrylate) Oligomers in THF/Toluene Mixtures

Solvation influences both the stereoregularity and molecular weight distribution (MWD) of poly(tert-butyl methacrylate) (PtBMA) prepared by anionic polymerization of tBMA with a lithium counterion in THF/toluene mixed solvents at −78 °C. As a probe of the structural changes of the propagating specie...

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Veröffentlicht in:	Macromolecules 1999-08, Vol.32 (17), p.5477-5486
Hauptverfasser:	Zune, C, Dubois, P, Grandjean, J, Kriz, J, Dybal, J, Lochmann, L, Janata, M, Vlcek, P, Jérôme, R
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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