Synthesis and Characterization of Highly Efficient Photorefractive Polymer Composites with Long Phase Stability
We have synthesized the chromophores 4-[(4‘-nitrophenyl)azo]-1,3-bis[(3‘‘- or 4‘‘-vinylbenzyl)oxy]benzene (NPADVBB) and 4-[(4‘-nitrophenyl)azo]-1,3-bis(benzyloxy)benzene (NPADB). New polymer composites based on the photoconductor poly(9-vinylcarbazole), the plasticizer 9-ethylcarbazole, NPADVBB, and...
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| Veröffentlicht in: | Macromolecules 1998-02, Vol.31 (3), p.734-739 |
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| container_title | Macromolecules |
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| creator | Hendrickx, E Wang, J. F Maldonado, J. L Volodin, B. L Sandalphon Mash, E. A Persoons, A Kippelen, B Peyghambarian, N |
| description | We have synthesized the chromophores 4-[(4‘-nitrophenyl)azo]-1,3-bis[(3‘‘- or 4‘‘-vinylbenzyl)oxy]benzene (NPADVBB) and 4-[(4‘-nitrophenyl)azo]-1,3-bis(benzyloxy)benzene (NPADB). New polymer composites based on the photoconductor poly(9-vinylcarbazole), the plasticizer 9-ethylcarbazole, NPADVBB, and the sensitizers 2,4,7-trinitro-9-fluorenone and (2,4,7-trinitro-9-fluorenylidene)malonitrile were prepared. Ellipsometric measurements and degenerate four-wave mixing experiments were performed at 633 and 830 nm. The composites showed excellent phase stability, and nearly complete diffraction was observed at 633 nm. The two-beam coupling gain was limited by the small phase shift between the interference pattern and the index grating. |
| doi_str_mv | 10.1021/ma9714777 |
| format | Article |
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F ; Maldonado, J. L ; Volodin, B. L ; Sandalphon ; Mash, E. A ; Persoons, A ; Kippelen, B ; Peyghambarian, N</creator><creatorcontrib>Hendrickx, E ; Wang, J. F ; Maldonado, J. L ; Volodin, B. L ; Sandalphon ; Mash, E. A ; Persoons, A ; Kippelen, B ; Peyghambarian, N</creatorcontrib><description>We have synthesized the chromophores 4-[(4‘-nitrophenyl)azo]-1,3-bis[(3‘‘- or 4‘‘-vinylbenzyl)oxy]benzene (NPADVBB) and 4-[(4‘-nitrophenyl)azo]-1,3-bis(benzyloxy)benzene (NPADB). New polymer composites based on the photoconductor poly(9-vinylcarbazole), the plasticizer 9-ethylcarbazole, NPADVBB, and the sensitizers 2,4,7-trinitro-9-fluorenone and (2,4,7-trinitro-9-fluorenylidene)malonitrile were prepared. Ellipsometric measurements and degenerate four-wave mixing experiments were performed at 633 and 830 nm. The composites showed excellent phase stability, and nearly complete diffraction was observed at 633 nm. The two-beam coupling gain was limited by the small phase shift between the interference pattern and the index grating.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma9714777</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Blends ; Exact sciences and technology ; Forms of application and semi-finished materials ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>Macromolecules, 1998-02, Vol.31 (3), p.734-739</ispartof><rights>Copyright © 1998 American Chemical Society</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a324t-1b54e6a3884d30e8f016808a0003ea44f2208e7dd621650bfb7e3abe4d3ea47f3</citedby><cites>FETCH-LOGICAL-a324t-1b54e6a3884d30e8f016808a0003ea44f2208e7dd621650bfb7e3abe4d3ea47f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ma9714777$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ma9714777$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2150126$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Hendrickx, E</creatorcontrib><creatorcontrib>Wang, J. 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Ellipsometric measurements and degenerate four-wave mixing experiments were performed at 633 and 830 nm. The composites showed excellent phase stability, and nearly complete diffraction was observed at 633 nm. The two-beam coupling gain was limited by the small phase shift between the interference pattern and the index grating.</description><subject>Applied sciences</subject><subject>Blends</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNpt0L1u2zAQAGCiaIG6Toe-AYdkyKD2SEqiPAaCExcwUAN2g2zESSYtOrJokEwb5enDwIGnTDfcd7-E_GDwkwFnvw44kyyXUn4iE1ZwyIpKFJ_JBIDn2YzP5FfyLYQ9AGNFLibErcchdjrYQHHY0rpDj23U3r5gtG6gztCF3XX9SOfG2NbqIdJV56Lz2rxJ-0_TlevHg_a0doejCzbqQP_b2NGlG3YJY9B0HbGxvY3jBflisA_6-3uckr-38029yJZ_7n7XN8sMBc9jxpoi1yWKqsq3AnRlgJUVVAgAQmOeG86h0nK7LTkrC2hMI7XARied0tKIKbk-9W29CyEtq47eHtCPioF6-5Q6fyrZy5M9YmixT3cNrQ3nAs4KYLxMLDsxG6J-PqfRP6pSClmozWqt2EO9rFjN1H3yVyePbVB79-SHdPAH418Be6-Epg</recordid><startdate>19980210</startdate><enddate>19980210</enddate><creator>Hendrickx, E</creator><creator>Wang, J. 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A ; Persoons, A ; Kippelen, B ; Peyghambarian, N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a324t-1b54e6a3884d30e8f016808a0003ea44f2208e7dd621650bfb7e3abe4d3ea47f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Blends</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hendrickx, E</creatorcontrib><creatorcontrib>Wang, J. F</creatorcontrib><creatorcontrib>Maldonado, J. L</creatorcontrib><creatorcontrib>Volodin, B. L</creatorcontrib><creatorcontrib>Sandalphon</creatorcontrib><creatorcontrib>Mash, E. A</creatorcontrib><creatorcontrib>Persoons, A</creatorcontrib><creatorcontrib>Kippelen, B</creatorcontrib><creatorcontrib>Peyghambarian, N</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hendrickx, E</au><au>Wang, J. F</au><au>Maldonado, J. L</au><au>Volodin, B. L</au><au>Sandalphon</au><au>Mash, E. A</au><au>Persoons, A</au><au>Kippelen, B</au><au>Peyghambarian, N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of Highly Efficient Photorefractive Polymer Composites with Long Phase Stability</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>1998-02-10</date><risdate>1998</risdate><volume>31</volume><issue>3</issue><spage>734</spage><epage>739</epage><pages>734-739</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>We have synthesized the chromophores 4-[(4‘-nitrophenyl)azo]-1,3-bis[(3‘‘- or 4‘‘-vinylbenzyl)oxy]benzene (NPADVBB) and 4-[(4‘-nitrophenyl)azo]-1,3-bis(benzyloxy)benzene (NPADB). New polymer composites based on the photoconductor poly(9-vinylcarbazole), the plasticizer 9-ethylcarbazole, NPADVBB, and the sensitizers 2,4,7-trinitro-9-fluorenone and (2,4,7-trinitro-9-fluorenylidene)malonitrile were prepared. Ellipsometric measurements and degenerate four-wave mixing experiments were performed at 633 and 830 nm. The composites showed excellent phase stability, and nearly complete diffraction was observed at 633 nm. The two-beam coupling gain was limited by the small phase shift between the interference pattern and the index grating.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma9714777</doi><tpages>6</tpages></addata></record> |
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| source | American Chemical Society Journals |
| subjects | Applied sciences Blends Exact sciences and technology Forms of application and semi-finished materials Polymer industry, paints, wood Technology of polymers |
| title | Synthesis and Characterization of Highly Efficient Photorefractive Polymer Composites with Long Phase Stability |
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