Controlled Functionalization of Polystyrene:  Introduction of Reactive Groups by Multisite Metalation with Superbase and Reaction with Electrophiles

The controlled functionalization of polystyrene using a process of metalation with a potassium superbase followed by reaction with electrophiles is described. The method is advantageous because metalation is extremely efficient, occurring rapidly even at room temperature, and the degree of functiona...

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Veröffentlicht in:Macromolecules 1996-02, Vol.29 (5), p.1767-1771
Hauptverfasser: Lochmann, Lubomir, Fréchet, Jean M. J
Format: Artikel
Sprache:eng
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