Mark−Houwink−Kuhn−Sakurada Exponent at the ϑ Condition. Its Invariancy with Respect to the Cross-Sectional Dimensions of Polymer Chains
The question raised by Fujita has been examined, namely why the intrinsic viscosity of many polymers at the ϑ condition [η]0 is proportional to M 1/2 over a broad range of molecular weights. An explanation is proposed, based on a combination of the theory of the wormlike cylinder model with reported...
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Veröffentlicht in: | Macromolecules 1996-03, Vol.29 (6), p.2265-2268 |
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Format: | Artikel |
Sprache: | eng |
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