Polyaniline and Polypyrrole Templated on Self-Assembled Acidic Block Copolymers

Polyaniline and Polypyrrole Templated on Self-Assembled Acidic Block Copolymers

A method was developed for utilizing block copolymers that combine an acidic block, 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPSA), and an acrylate block, n-butyl, ethyl, or methyl acrylate, as templates for acid-doped conducting polymers such as polyaniline (PANI) or polypyrrole (PPY). PANI t...

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Veröffentlicht in:Macromolecules 2009-11, Vol.42 (21), p.8129-8137
Hauptverfasser: McCullough, Lynne A, Dufour, Bruno, Matyjaszewski, Krzysztof
Format: Artikel
Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
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container_end_page 8137
container_issue 21
container_start_page 8129
container_title Macromolecules
container_volume 42
creator McCullough, Lynne A
Dufour, Bruno
Matyjaszewski, Krzysztof
description A method was developed for utilizing block copolymers that combine an acidic block, 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPSA), and an acrylate block, n-butyl, ethyl, or methyl acrylate, as templates for acid-doped conducting polymers such as polyaniline (PANI) or polypyrrole (PPY). PANI templated with diblock copolymers dissolved in dichloroacetic acid results in the formation of high-conductivity materials (30 S/cm) that possess a greater degree of flexibility than pure PANI (between 20% and 50% elongation at ∼4 MPa). Triblock copolymers were used as templates for the oxidative polymerization of PANI and PPY to form in situ conducting polymer composites with conductivities of ∼0.1 S/cm.
doi_str_mv 10.1021/ma901560k
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PANI templated with diblock copolymers dissolved in dichloroacetic acid results in the formation of high-conductivity materials (30 S/cm) that possess a greater degree of flexibility than pure PANI (between 20% and 50% elongation at ∼4 MPa). 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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Polyaniline and Polypyrrole Templated on Self-Assembled Acidic Block Copolymers
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