Controlled Synthesis of High Molecular Weight Polyacrylates Having a Dumbbell Topology

Well-defined high molecular weight (MW) (M n ∼ 500 000, M w/M n < 1.2) dumbbell-shaped copolymers based on butyl acrylates (BA) were synthesized by atom transfer radical polymerization (ATRP) in acetone. The synthesis was carried out by polymerization of BA initiated by a difunctional ATRP initia...

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Veröffentlicht in:Macromolecules 2009-09, Vol.42 (18), p.6873-6877
Hauptverfasser: Dimitrov, Philip, Iyer, Pradeep, Bharadwaj, Rishikesh, Mallya, Prakash, Hogen-Esch, Thieo E
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Sprache:eng
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