Chain-Length-Dependent Termination in n-Butyl Methacrylate and tert-Butyl Methacrylate Bulk Homopolymerizations Studied via SP-PLP-ESR

The chain-length dependence of the termination rate coefficient, k t, of bulk homopolymerizations of n-butyl methacrylate (n-BMA) and tert-butyl methacrylate (t-BMA) at ambient pressure and temperatures between −30 and 60 °C has been studied via the single pulse−pulsed laser polymerization−electron...

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Veröffentlicht in:	Macromolecules 2009-01, Vol.42 (2), p.481-488
Hauptverfasser:	Barth, Johannes, Buback, Michael, Hesse, Pascal, Sergeeva, Tatiana
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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