C 2-Symmetric Ni(II) α-Diimines Featuring Cumyl-Derived Ligands: Synthesis of Improved Elastomeric Regioblock Polypropylenes

A series of chiral, nickel α-diimine complexes featuring ligands based on bulky cumyl-substituted aniline moieties was synthesized. Each complex was capable of polymerizing propylene upon activation with methylaluminoxane (MAO). The catalysts were shown to be highly regioregular and isoselective for...

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Veröffentlicht in:	Macromolecules 2008-12, Vol.41 (24), p.9548-9555
Hauptverfasser:	Rose, Jeffrey M, Deplace, Fanny, Lynd, Nathaniel A, Wang, Zhigang, Hotta, Atsushi, Lobkovsky, Emil B, Kramer, Edward J, Coates, Geoffrey W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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