Specific Polymerization Mechanism Involving β-Scission of Mid-Chain Radical Yielding Oligomers in the Free-Radical Polymerization of Vinyl Ethers

Butyl vinyl ether (BVE) was polymerized radically, and the resultant oligomeric poly(BVE)s were characterized mainly using MALDI-TOF-MS spectrometry. For a further structural identification, the poly(BVE) obtained in bulk was subsequently subjected to 1H NMR measurement. Notably, an intensive peak a...

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Veröffentlicht in:	Macromolecules 2008-10, Vol.41 (20), p.7347-7351
Hauptverfasser:	Kumagai, Takeo, Kagawa, Chihiro, Aota, Hiroyuki, Takeda, Yoshiki, Kawasaki, Hideya, Arakawa, Ryuichi, Matsumoto, Akira
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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