Modeling and Understanding Closed-Loop Liquid−Liquid Immiscibility in Aqueous Solutions of Poly(ethylene glycol) Using the SAFT-VR Approach with Transferable Parameters

The closed-loop liquid−liquid fluid phase equilibria of aqueous solutions of poly(ethylene glycol) (PEG) binary mixtures are studied using the statistical associating fluid theory for potentials of variable range (SAFT-VR). A molecular model of the mixture is developed which takes into account the d...

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Veröffentlicht in:Macromolecules 2008-09, Vol.41 (17), p.6582-6595
Hauptverfasser: Clark, Gary N. I, Galindo, Amparo, Jackson, George, Rogers, Steve, Burgess, Andrew N
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Sprache:eng
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