Controlled Functionalization of Crystalline Polystyrenes via Activation of Aromatic C−H Bonds

The iridium-catalyzed functionalization of the C−H bond of commercial polystyrenes with three types of tacticities (syndiotactic, isotactic, atactic) using boron reagents is reported. The boronate ester group in the polystyrene was further converted to hydroxy and arene via oxidation and Suzuki−Miya...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Macromolecules 2007-11, Vol.40 (24), p.8600-8608
Hauptverfasser:	Shin, Jihoon, Jensen, Stephen M, Ju, Jinhun, Lee, Sunwoo, Xue, Zhigang, Noh, Seok Kyun, Bae, Chulsung
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical modifications Chemical reactions and properties Exact sciences and technology Organic polymers Physicochemistry of polymers
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!