Triggered Precision Benzoxazine Film Formation by Thermally Induced Destabilization of Benzoxazine Nanodroplets Using a LCST-Bearing Surfactant

Triggered Precision Benzoxazine Film Formation by Thermally Induced Destabilization of Benzoxazine Nanodroplets Using a LCST-Bearing Surfactant

A novel method for film formation has been developed utilizing miniemulsion properties. The process destabilizes emulsion droplets in a controlled fashion and deposits the droplets onto a substrate to form a resin film. By utilizing a polymeric stabilizer with lower critical solution temperature (LC...

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Veröffentlicht in:Macromolecules 2014-05, Vol.47 (10), p.3297-3305
Hauptverfasser: Chiou, Kevin, Froimowicz, Pablo, Landfester, Katharina, Taden, Andreas, Ishida, Hatsuo
Format: Artikel
Sprache:eng
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Applied sciences
Exact sciences and technology
Forms of application and semi-finished materials
Polymer industry, paints, wood
Sheets and films
Technology of polymers
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container_end_page 3305
container_issue 10
container_start_page 3297
container_title Macromolecules
container_volume 47
creator Chiou, Kevin
Froimowicz, Pablo
Landfester, Katharina
Taden, Andreas
Ishida, Hatsuo
description A novel method for film formation has been developed utilizing miniemulsion properties. The process destabilizes emulsion droplets in a controlled fashion and deposits the droplets onto a substrate to form a resin film. By utilizing a polymeric stabilizer with lower critical solution temperature (LCST) behavior as functional protective colloid, the emulsion is designed to destabilize when the system reaches a set temperature. Using LCST-bearing protective colloids, benzoxazine resin films are formed and polymerized. By design, the utilized polymeric stabilizer contains benzoxazine groups, which are covalently incorporated into the matrix as a reactant. The resulting film is similar to those formed following a solution casting method. The novel process offers the possibility of applying precision micro-optic coating eliminating the edge effect as well as forming homogeneous film thickness aided by the near monodisperse emulsion particle sizes.
doi_str_mv 10.1021/ma500386z
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subjects Applied sciences
Exact sciences and technology
Forms of application and semi-finished materials
Polymer industry, paints, wood
Sheets and films
Technology of polymers
title Triggered Precision Benzoxazine Film Formation by Thermally Induced Destabilization of Benzoxazine Nanodroplets Using a LCST-Bearing Surfactant
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