Synthesis of Highly Monodisperse Surface-Functional Microspheres by Photoinitiated RAFT Dispersion Polymerization Using Macro-RAFT Agents

Highly monodisperse PMMA microspheres have been synthesized by photoinitiated RAFT dispersion polymerization in the presence of a Macro-RAFT agent and a small molecular RAFT agent. A particle yield of over 90% was achieved within 3 h under UV irradiation at room temperature. The Macro-RAFT agent act...

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Veröffentlicht in:Macromolecules 2013-11, Vol.46 (21), p.8441-8448
Hauptverfasser: Tan, Jianbo, Rao, Xin, Yang, Jianwen, Zeng, Zhaohua
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Sprache:eng
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