Donor–Acceptor Semiconducting Polymers Containing Benzodithiophene with Bithienyl Substituents

Synthesis and photovoltaic properties of two donor–acceptor polymers containing benzodithiophene with 3,3′,5-trihexylbithienyl substituents are reported. Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor pol...

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Veröffentlicht in:Macromolecules 2012-10, Vol.45 (19), p.7855-7862
Hauptverfasser: Kularatne, Ruvini S, Sista, Prakash, Nguyen, Hien Q, Bhatt, Mahesh P, Biewer, Michael C, Stefan, Mihaela C
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container_end_page 7862
container_issue 19
container_start_page 7855
container_title Macromolecules
container_volume 45
creator Kularatne, Ruvini S
Sista, Prakash
Nguyen, Hien Q
Bhatt, Mahesh P
Biewer, Michael C
Stefan, Mihaela C
description Synthesis and photovoltaic properties of two donor–acceptor polymers containing benzodithiophene with 3,3′,5-trihexylbithienyl substituents are reported. Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor polymers. The photovoltaic properties of the synthesized donor–acceptor polymers were investigated in bulk heterojunction solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) acceptor.
doi_str_mv 10.1021/ma301624t
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source American Chemical Society Journals
subjects Applied sciences
Energy
Exact sciences and technology
Natural energy
Organic polymers
Photovoltaic conversion
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
Solar cells. Photoelectrochemical cells
Solar energy
title Donor–Acceptor Semiconducting Polymers Containing Benzodithiophene with Bithienyl Substituents
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