Donor–Acceptor Semiconducting Polymers Containing Benzodithiophene with Bithienyl Substituents
Synthesis and photovoltaic properties of two donor–acceptor polymers containing benzodithiophene with 3,3′,5-trihexylbithienyl substituents are reported. Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor pol...
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Veröffentlicht in: | Macromolecules 2012-10, Vol.45 (19), p.7855-7862 |
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container_title | Macromolecules |
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creator | Kularatne, Ruvini S Sista, Prakash Nguyen, Hien Q Bhatt, Mahesh P Biewer, Michael C Stefan, Mihaela C |
description | Synthesis and photovoltaic properties of two donor–acceptor polymers containing benzodithiophene with 3,3′,5-trihexylbithienyl substituents are reported. Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor polymers. The photovoltaic properties of the synthesized donor–acceptor polymers were investigated in bulk heterojunction solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) acceptor. |
doi_str_mv | 10.1021/ma301624t |
format | Article |
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Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor polymers. The photovoltaic properties of the synthesized donor–acceptor polymers were investigated in bulk heterojunction solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) acceptor.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma301624t</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Energy ; Exact sciences and technology ; Natural energy ; Organic polymers ; Photovoltaic conversion ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Solar cells. 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Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor polymers. The photovoltaic properties of the synthesized donor–acceptor polymers were investigated in bulk heterojunction solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) acceptor.</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Organic polymers</subject><subject>Photovoltaic conversion</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solar cells. 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Photoelectrochemical cells</topic><topic>Solar energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kularatne, Ruvini S</creatorcontrib><creatorcontrib>Sista, Prakash</creatorcontrib><creatorcontrib>Nguyen, Hien Q</creatorcontrib><creatorcontrib>Bhatt, Mahesh P</creatorcontrib><creatorcontrib>Biewer, Michael C</creatorcontrib><creatorcontrib>Stefan, Mihaela C</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kularatne, Ruvini S</au><au>Sista, Prakash</au><au>Nguyen, Hien Q</au><au>Bhatt, Mahesh P</au><au>Biewer, Michael C</au><au>Stefan, Mihaela C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Donor–Acceptor Semiconducting Polymers Containing Benzodithiophene with Bithienyl Substituents</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2012-10-09</date><risdate>2012</risdate><volume>45</volume><issue>19</issue><spage>7855</spage><epage>7862</epage><pages>7855-7862</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>Synthesis and photovoltaic properties of two donor–acceptor polymers containing benzodithiophene with 3,3′,5-trihexylbithienyl substituents are reported. Benzo[c][1,2,5]thiadiazole and 5-hexylthieno[3,4-c]pyrrole-4,6-dione were used as acceptor building blocks for the synthesis of donor–acceptor polymers. The photovoltaic properties of the synthesized donor–acceptor polymers were investigated in bulk heterojunction solar cells with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) acceptor.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma301624t</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences Energy Exact sciences and technology Natural energy Organic polymers Photovoltaic conversion Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Solar cells. Photoelectrochemical cells Solar energy |
title | Donor–Acceptor Semiconducting Polymers Containing Benzodithiophene with Bithienyl Substituents |
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