Synthesis and Characterization of a Novel Naphthodithiophene-Based Copolymer for Use in Polymer Solar Cells
A novel naphtho[2,3-b:6,7-d′]dithiophene (NDT)-based copolymer, poly[4,9-bis(2-ethylhexyloxy)naphtho[2,3-b:6,7-d′]dithiophene-2,7-diyl-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P1), was synthesized and characterized for use in polymer solar cells. We systematically investigated...
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| Veröffentlicht in: | Macromolecules 2012-09, Vol.45 (17), p.6938-6945 |
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| container_title | Macromolecules |
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| creator | Sanjaykumar S R Badgujar, Sachin Song, Chang Eun Shin, Won Suk Moon, Sang-Jin Kang, In-Nam Lee, Jaemin Cho, Shinuk Lee, Sang Kyu Lee, Jong-Cheol |
| description | A novel naphtho[2,3-b:6,7-d′]dithiophene (NDT)-based copolymer, poly[4,9-bis(2-ethylhexyloxy)naphtho[2,3-b:6,7-d′]dithiophene-2,7-diyl-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P1), was synthesized and characterized for use in polymer solar cells. We systematically investigated the synthesis, thermal stability, optical and electrochemical properties, field-effect carrier mobilities, and photovoltaic characteristics of the resulting polymer. The properties of the NDT-based polymer were compared with those of poly[4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P2) prepared via the same synthetic procedure. Polymer solar cells made from the new polymer, P1, yielded a power conversion efficiency of 4.0% with a short-circuit current density of 11.54 mA/cm2, an open-circuit voltage of 0.69 V, and a fill factor of 0.50 under AM 1.5 G irradiation (100 mW/cm2). |
| doi_str_mv | 10.1021/ma301312d |
| format | Article |
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We systematically investigated the synthesis, thermal stability, optical and electrochemical properties, field-effect carrier mobilities, and photovoltaic characteristics of the resulting polymer. The properties of the NDT-based polymer were compared with those of poly[4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P2) prepared via the same synthetic procedure. Polymer solar cells made from the new polymer, P1, yielded a power conversion efficiency of 4.0% with a short-circuit current density of 11.54 mA/cm2, an open-circuit voltage of 0.69 V, and a fill factor of 0.50 under AM 1.5 G irradiation (100 mW/cm2).</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma301312d</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Energy ; Exact sciences and technology ; Natural energy ; Organic polymers ; Photovoltaic conversion ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Solar cells. Photoelectrochemical cells ; Solar energy</subject><ispartof>Macromolecules, 2012-09, Vol.45 (17), p.6938-6945</ispartof><rights>Copyright © 2012 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a355t-fb9bf707b5567d51a4223ec32889bb13c1a8f400d99ec968c408c0c08099e4e03</citedby><cites>FETCH-LOGICAL-a355t-fb9bf707b5567d51a4223ec32889bb13c1a8f400d99ec968c408c0c08099e4e03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ma301312d$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ma301312d$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27078,27926,27927,56740,56790</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26351720$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sanjaykumar S R</creatorcontrib><creatorcontrib>Badgujar, Sachin</creatorcontrib><creatorcontrib>Song, Chang Eun</creatorcontrib><creatorcontrib>Shin, Won Suk</creatorcontrib><creatorcontrib>Moon, Sang-Jin</creatorcontrib><creatorcontrib>Kang, In-Nam</creatorcontrib><creatorcontrib>Lee, Jaemin</creatorcontrib><creatorcontrib>Cho, Shinuk</creatorcontrib><creatorcontrib>Lee, Sang Kyu</creatorcontrib><creatorcontrib>Lee, Jong-Cheol</creatorcontrib><title>Synthesis and Characterization of a Novel Naphthodithiophene-Based Copolymer for Use in Polymer Solar Cells</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>A novel naphtho[2,3-b:6,7-d′]dithiophene (NDT)-based copolymer, poly[4,9-bis(2-ethylhexyloxy)naphtho[2,3-b:6,7-d′]dithiophene-2,7-diyl-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P1), was synthesized and characterized for use in polymer solar cells. We systematically investigated the synthesis, thermal stability, optical and electrochemical properties, field-effect carrier mobilities, and photovoltaic characteristics of the resulting polymer. The properties of the NDT-based polymer were compared with those of poly[4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P2) prepared via the same synthetic procedure. Polymer solar cells made from the new polymer, P1, yielded a power conversion efficiency of 4.0% with a short-circuit current density of 11.54 mA/cm2, an open-circuit voltage of 0.69 V, and a fill factor of 0.50 under AM 1.5 G irradiation (100 mW/cm2).</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Organic polymers</subject><subject>Photovoltaic conversion</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkM9LwzAcxYMoOKcH_4NcPHiofpM0a3vU4i8YU5g7l2_ThGZ2SUmqMP96Kxvz4unB4_MevEfIJYMbBpzdblAAE4w3R2TCJIdE5kIekwkAT5OCF9kpOYtxDcCYTMWEfCy3bmh1tJGia2jZYkA16GC_cbDeUW8o0oX_0h1dYN8OrW_s0Frft9rp5B6jHkO-9912owM1PtBV1NQ6-ra3lr7DQEvddfGcnBjsor7Y65SsHh_ey-dk_vr0Ut7NExRSDompi9pkkNVSzrJGMkw5F1oJnudFXTOhGOYmBWiKQqtilqsUcgUKchiNVIOYkutdrwo-xqBN1Qe7wbCtGFS_L1WHl0b2asf2GBV2JqBTNh4CfCYkyzj8cahitfafwY0L_un7AVqWc48</recordid><startdate>20120911</startdate><enddate>20120911</enddate><creator>Sanjaykumar S R</creator><creator>Badgujar, Sachin</creator><creator>Song, Chang Eun</creator><creator>Shin, Won Suk</creator><creator>Moon, Sang-Jin</creator><creator>Kang, In-Nam</creator><creator>Lee, Jaemin</creator><creator>Cho, Shinuk</creator><creator>Lee, Sang Kyu</creator><creator>Lee, Jong-Cheol</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120911</creationdate><title>Synthesis and Characterization of a Novel Naphthodithiophene-Based Copolymer for Use in Polymer Solar Cells</title><author>Sanjaykumar S R ; Badgujar, Sachin ; Song, Chang Eun ; Shin, Won Suk ; Moon, Sang-Jin ; Kang, In-Nam ; Lee, Jaemin ; Cho, Shinuk ; Lee, Sang Kyu ; Lee, Jong-Cheol</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a355t-fb9bf707b5567d51a4223ec32889bb13c1a8f400d99ec968c408c0c08099e4e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Natural energy</topic><topic>Organic polymers</topic><topic>Photovoltaic conversion</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sanjaykumar S R</creatorcontrib><creatorcontrib>Badgujar, Sachin</creatorcontrib><creatorcontrib>Song, Chang Eun</creatorcontrib><creatorcontrib>Shin, Won Suk</creatorcontrib><creatorcontrib>Moon, Sang-Jin</creatorcontrib><creatorcontrib>Kang, In-Nam</creatorcontrib><creatorcontrib>Lee, Jaemin</creatorcontrib><creatorcontrib>Cho, Shinuk</creatorcontrib><creatorcontrib>Lee, Sang Kyu</creatorcontrib><creatorcontrib>Lee, Jong-Cheol</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sanjaykumar S R</au><au>Badgujar, Sachin</au><au>Song, Chang Eun</au><au>Shin, Won Suk</au><au>Moon, Sang-Jin</au><au>Kang, In-Nam</au><au>Lee, Jaemin</au><au>Cho, Shinuk</au><au>Lee, Sang Kyu</au><au>Lee, Jong-Cheol</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of a Novel Naphthodithiophene-Based Copolymer for Use in Polymer Solar Cells</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2012-09-11</date><risdate>2012</risdate><volume>45</volume><issue>17</issue><spage>6938</spage><epage>6945</epage><pages>6938-6945</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>A novel naphtho[2,3-b:6,7-d′]dithiophene (NDT)-based copolymer, poly[4,9-bis(2-ethylhexyloxy)naphtho[2,3-b:6,7-d′]dithiophene-2,7-diyl-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P1), was synthesized and characterized for use in polymer solar cells. We systematically investigated the synthesis, thermal stability, optical and electrochemical properties, field-effect carrier mobilities, and photovoltaic characteristics of the resulting polymer. The properties of the NDT-based polymer were compared with those of poly[4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b′]dithiophene-alt-1,3-(5-heptadecan-9-yl)-4H-thieno[3,4-c]pyrrole-4,6-dione] (P2) prepared via the same synthetic procedure. Polymer solar cells made from the new polymer, P1, yielded a power conversion efficiency of 4.0% with a short-circuit current density of 11.54 mA/cm2, an open-circuit voltage of 0.69 V, and a fill factor of 0.50 under AM 1.5 G irradiation (100 mW/cm2).</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma301312d</doi><tpages>8</tpages></addata></record> |
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| subjects | Applied sciences Energy Exact sciences and technology Natural energy Organic polymers Photovoltaic conversion Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Solar cells. Photoelectrochemical cells Solar energy |
| title | Synthesis and Characterization of a Novel Naphthodithiophene-Based Copolymer for Use in Polymer Solar Cells |
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