New Degradable Alternating Copolymers from Naturally Occurring Aldehydes: Well-Controlled Cationic Copolymerization and Complete Degradation

Three naturally occurring conjugated aldehydes, (1R)-(−)-myrtenal, (S)-(−)-perillaldehyde, and β-cyclocitral, were cationically copolymerized with isobutyl vinyl ether using the EtSO3H/GaCl3 initiating system in the presence of 1,4-dioxane as an added Lewis base. Alternating copolymerization proceed...

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Veröffentlicht in:	Macromolecules 2012-05, Vol.45 (10), p.4060-4068
Hauptverfasser:	Ishido, Yasushi, Kanazawa, Arihiro, Kanaoka, Shokyoku, Aoshima, Sadahito
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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