Members of CMY Color Space: Cyan and Magenta Colored Polymers Based on Oxadiazole Acceptor Unit

In this study, three novel oxadiazole-based polymers were synthesized and their electrochemical and optical properties were investigated. The polymers were found to have both p- and n-type doping properties accompanied by electrochromic response. Two polymer films exhibit cyan and magenta colors, wh...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Macromolecules 2012-01, Vol.45 (2), p.729-734
Hauptverfasser: Özkut, Merve İçli, Algi, Melek Pamuk, Öztaş, Zahide, Algi, Fatih, Önal, Ahmet M, Cihaner, Atilla
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 734
container_issue 2
container_start_page 729
container_title Macromolecules
container_volume 45
creator Özkut, Merve İçli
Algi, Melek Pamuk
Öztaş, Zahide
Algi, Fatih
Önal, Ahmet M
Cihaner, Atilla
description In this study, three novel oxadiazole-based polymers were synthesized and their electrochemical and optical properties were investigated. The polymers were found to have both p- and n-type doping properties accompanied by electrochromic response. Two polymer films exhibit cyan and magenta colors, which constitute two legs of CMY color spaces, in their neutral states and they are soluble in common-organic solvents. According to the color mixing theory, all colors in the visible spectrum including black color can be obtained by using these polymers with a yellow colored electrochromic polymer. Among these polymers, the polymer bearing propyledioxythiophene donor units has some superior properties like high stability (it retains 94% of its electroactivity after 2000 cycles), solubility, and high coloration efficiency (230 cm2/C), whereas as expected ethylenedioxythiophene containing one has the lowest band gap as 1.08 eV.
doi_str_mv 10.1021/ma202331t
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_ma202331t</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d121402554</sourcerecordid><originalsourceid>FETCH-LOGICAL-a289t-abf5b3b90a846ab82ff9143b188f75755065fc9488585a6c5fbf2d2d0439aedb3</originalsourceid><addsrcrecordid>eNptkE1Lw0AQhhdRsFYP_oO9ePAQ3c9k462G-gEtFbQHT2F2syspSTbsRrD-elMq9eJpGOZ5H5gXoUtKbihh9LYFRhjndDhCEyoZSaTi8hhNCGEiyVmenaKzGDeEUCoFn6ByaVttQ8Te4WL5jgvf-IBfezD2Dhdb6DB0FV7Ch-0G2F9thV98s213qXuI4-o7vPqCqoZv31g8M8b2w2hZd_Vwjk4cNNFe_M4pWj_M34qnZLF6fC5miwSYyocEtJOa65yAEiloxZzLqeCaKuUymUlJUulMLpSSSkJqpNOOVawigudgK82n6HrvNcHHGKwr-1C3ELYlJeWumfLQzMhe7dkeooHGBehMHQ8BJkWWEkb-ODCx3PjP0I0f_OP7AZSYbk8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Members of CMY Color Space: Cyan and Magenta Colored Polymers Based on Oxadiazole Acceptor Unit</title><source>American Chemical Society Journals</source><creator>Özkut, Merve İçli ; Algi, Melek Pamuk ; Öztaş, Zahide ; Algi, Fatih ; Önal, Ahmet M ; Cihaner, Atilla</creator><creatorcontrib>Özkut, Merve İçli ; Algi, Melek Pamuk ; Öztaş, Zahide ; Algi, Fatih ; Önal, Ahmet M ; Cihaner, Atilla</creatorcontrib><description>In this study, three novel oxadiazole-based polymers were synthesized and their electrochemical and optical properties were investigated. The polymers were found to have both p- and n-type doping properties accompanied by electrochromic response. Two polymer films exhibit cyan and magenta colors, which constitute two legs of CMY color spaces, in their neutral states and they are soluble in common-organic solvents. According to the color mixing theory, all colors in the visible spectrum including black color can be obtained by using these polymers with a yellow colored electrochromic polymer. Among these polymers, the polymer bearing propyledioxythiophene donor units has some superior properties like high stability (it retains 94% of its electroactivity after 2000 cycles), solubility, and high coloration efficiency (230 cm2/C), whereas as expected ethylenedioxythiophene containing one has the lowest band gap as 1.08 eV.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma202331t</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Exact sciences and technology ; Physicochemistry of polymers ; Polymerization ; Polymers and radiations</subject><ispartof>Macromolecules, 2012-01, Vol.45 (2), p.729-734</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-abf5b3b90a846ab82ff9143b188f75755065fc9488585a6c5fbf2d2d0439aedb3</citedby><cites>FETCH-LOGICAL-a289t-abf5b3b90a846ab82ff9143b188f75755065fc9488585a6c5fbf2d2d0439aedb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ma202331t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ma202331t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=25476020$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Özkut, Merve İçli</creatorcontrib><creatorcontrib>Algi, Melek Pamuk</creatorcontrib><creatorcontrib>Öztaş, Zahide</creatorcontrib><creatorcontrib>Algi, Fatih</creatorcontrib><creatorcontrib>Önal, Ahmet M</creatorcontrib><creatorcontrib>Cihaner, Atilla</creatorcontrib><title>Members of CMY Color Space: Cyan and Magenta Colored Polymers Based on Oxadiazole Acceptor Unit</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>In this study, three novel oxadiazole-based polymers were synthesized and their electrochemical and optical properties were investigated. The polymers were found to have both p- and n-type doping properties accompanied by electrochromic response. Two polymer films exhibit cyan and magenta colors, which constitute two legs of CMY color spaces, in their neutral states and they are soluble in common-organic solvents. According to the color mixing theory, all colors in the visible spectrum including black color can be obtained by using these polymers with a yellow colored electrochromic polymer. Among these polymers, the polymer bearing propyledioxythiophene donor units has some superior properties like high stability (it retains 94% of its electroactivity after 2000 cycles), solubility, and high coloration efficiency (230 cm2/C), whereas as expected ethylenedioxythiophene containing one has the lowest band gap as 1.08 eV.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers and radiations</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkE1Lw0AQhhdRsFYP_oO9ePAQ3c9k462G-gEtFbQHT2F2syspSTbsRrD-elMq9eJpGOZ5H5gXoUtKbihh9LYFRhjndDhCEyoZSaTi8hhNCGEiyVmenaKzGDeEUCoFn6ByaVttQ8Te4WL5jgvf-IBfezD2Dhdb6DB0FV7Ch-0G2F9thV98s213qXuI4-o7vPqCqoZv31g8M8b2w2hZd_Vwjk4cNNFe_M4pWj_M34qnZLF6fC5miwSYyocEtJOa65yAEiloxZzLqeCaKuUymUlJUulMLpSSSkJqpNOOVawigudgK82n6HrvNcHHGKwr-1C3ELYlJeWumfLQzMhe7dkeooHGBehMHQ8BJkWWEkb-ODCx3PjP0I0f_OP7AZSYbk8</recordid><startdate>20120124</startdate><enddate>20120124</enddate><creator>Özkut, Merve İçli</creator><creator>Algi, Melek Pamuk</creator><creator>Öztaş, Zahide</creator><creator>Algi, Fatih</creator><creator>Önal, Ahmet M</creator><creator>Cihaner, Atilla</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120124</creationdate><title>Members of CMY Color Space: Cyan and Magenta Colored Polymers Based on Oxadiazole Acceptor Unit</title><author>Özkut, Merve İçli ; Algi, Melek Pamuk ; Öztaş, Zahide ; Algi, Fatih ; Önal, Ahmet M ; Cihaner, Atilla</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-abf5b3b90a846ab82ff9143b188f75755065fc9488585a6c5fbf2d2d0439aedb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers and radiations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Özkut, Merve İçli</creatorcontrib><creatorcontrib>Algi, Melek Pamuk</creatorcontrib><creatorcontrib>Öztaş, Zahide</creatorcontrib><creatorcontrib>Algi, Fatih</creatorcontrib><creatorcontrib>Önal, Ahmet M</creatorcontrib><creatorcontrib>Cihaner, Atilla</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Özkut, Merve İçli</au><au>Algi, Melek Pamuk</au><au>Öztaş, Zahide</au><au>Algi, Fatih</au><au>Önal, Ahmet M</au><au>Cihaner, Atilla</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Members of CMY Color Space: Cyan and Magenta Colored Polymers Based on Oxadiazole Acceptor Unit</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2012-01-24</date><risdate>2012</risdate><volume>45</volume><issue>2</issue><spage>729</spage><epage>734</epage><pages>729-734</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>In this study, three novel oxadiazole-based polymers were synthesized and their electrochemical and optical properties were investigated. The polymers were found to have both p- and n-type doping properties accompanied by electrochromic response. Two polymer films exhibit cyan and magenta colors, which constitute two legs of CMY color spaces, in their neutral states and they are soluble in common-organic solvents. According to the color mixing theory, all colors in the visible spectrum including black color can be obtained by using these polymers with a yellow colored electrochromic polymer. Among these polymers, the polymer bearing propyledioxythiophene donor units has some superior properties like high stability (it retains 94% of its electroactivity after 2000 cycles), solubility, and high coloration efficiency (230 cm2/C), whereas as expected ethylenedioxythiophene containing one has the lowest band gap as 1.08 eV.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma202331t</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0024-9297
ispartof Macromolecules, 2012-01, Vol.45 (2), p.729-734
issn 0024-9297
1520-5835
language eng
recordid cdi_crossref_primary_10_1021_ma202331t
source American Chemical Society Journals
subjects Applied sciences
Exact sciences and technology
Physicochemistry of polymers
Polymerization
Polymers and radiations
title Members of CMY Color Space: Cyan and Magenta Colored Polymers Based on Oxadiazole Acceptor Unit
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T23%3A41%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Members%20of%20CMY%20Color%20Space:%20Cyan%20and%20Magenta%20Colored%20Polymers%20Based%20on%20Oxadiazole%20Acceptor%20Unit&rft.jtitle=Macromolecules&rft.au=O%CC%88zkut,%20Merve%20I%CC%87c%CC%A7li&rft.date=2012-01-24&rft.volume=45&rft.issue=2&rft.spage=729&rft.epage=734&rft.pages=729-734&rft.issn=0024-9297&rft.eissn=1520-5835&rft.coden=MAMOBX&rft_id=info:doi/10.1021/ma202331t&rft_dat=%3Cacs_cross%3Ed121402554%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true