Localization of Critical Molar Ratio Intervals for Highly Branched Step-Growth Michael Addition Networks

Experimental stoichiometric gelation boundaries of a set of branched thiol to acrylate Michael addition polymerization systems were investigated, and the observed limits were compared to theoretical critical molar ratio (CMR) intervals. These CMR intervals were calculated via the Flory–Stockmayer eq...

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Veröffentlicht in:	Macromolecules 2011-07, Vol.44 (13), p.5123-5126
Hauptverfasser:	Platte, Daniela, Helbig, Uta, Houbertz, Ruth, Sextl, Gerhard
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polycondensation Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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