The Missing Lactam-Thermoresponsive and Biocompatible Poly(N-vinylpiperidone) Polymers by Xanthate-Mediated RAFT Polymerization

A new polymer poly(N-vinylpiperidone) (PVPip) (2 x , M n NMR 4.5−83 kDa) has been prepared by reversible addition−fragmentation chain-transfer (RAFT) polymerization using a xanthate as a chain-transfer agent. These polymers all exhibited sharp reversible cloud points (in the range 87 and 68 °C) whic...

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Veröffentlicht in:	Macromolecules 2011-02, Vol.44 (4), p.886-893
Hauptverfasser:	Ieong, Nga Sze, Redhead, Martin, Bosquillon, Cynthia, Alexander, Cameron, Kelland, Malcolm, O’Reilly, Rachel K
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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