Synthesis and Characterization of Thiophene-Containing Naphthalene Diimide n-Type Copolymers for OFET Applications
Naphthalene diimide (NDI) copolymers are attractive n-type materials for use in organic electronic devices. Four highly soluble NDI polymers are presentedeach differing only in the thiophene content comprising the material. Electron mobilities as high as 0.076 cm2 V−1 s−1 for the novel material PND...
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| Veröffentlicht in: | Macromolecules 2010-08, Vol.43 (15), p.6348-6352 |
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| container_title | Macromolecules |
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| creator | Durban, Matthew M Kazarinoff, Peter D Luscombe, Christine K |
| description | Naphthalene diimide (NDI) copolymers are attractive n-type materials for use in organic electronic devices. Four highly soluble NDI polymers are presentedeach differing only in the thiophene content comprising the material. Electron mobilities as high as 0.076 cm2 V−1 s−1 for the novel material PNDI-3Th are reported. Polymer crystallinity and general macromolecular order are shown to effectively improve by increasing the number of thiophene units within the polymer backbone. The structure−property relationship of NDI−thiophene copolymers is presented and discussed as it pertains to organic field effect transistor (OFET) performance. |
| doi_str_mv | 10.1021/ma100997g |
| format | Article |
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Four highly soluble NDI polymers are presentedeach differing only in the thiophene content comprising the material. Electron mobilities as high as 0.076 cm2 V−1 s−1 for the novel material PNDI-3Th are reported. Polymer crystallinity and general macromolecular order are shown to effectively improve by increasing the number of thiophene units within the polymer backbone. The structure−property relationship of NDI−thiophene copolymers is presented and discussed as it pertains to organic field effect transistor (OFET) performance.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma100997g</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Electronics ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Semiconductor electronics. Microelectronics. Optoelectronics. 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Four highly soluble NDI polymers are presentedeach differing only in the thiophene content comprising the material. Electron mobilities as high as 0.076 cm2 V−1 s−1 for the novel material PNDI-3Th are reported. Polymer crystallinity and general macromolecular order are shown to effectively improve by increasing the number of thiophene units within the polymer backbone. The structure−property relationship of NDI−thiophene copolymers is presented and discussed as it pertains to organic field effect transistor (OFET) performance.</description><subject>Applied sciences</subject><subject>Electronics</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Semiconductor electronics. Microelectronics. Optoelectronics. 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| ispartof | Macromolecules, 2010-08, Vol.43 (15), p.6348-6352 |
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| language | eng |
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| source | American Chemical Society (ACS) Journals |
| subjects | Applied sciences Electronics Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices Transistors |
| title | Synthesis and Characterization of Thiophene-Containing Naphthalene Diimide n-Type Copolymers for OFET Applications |
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