Stereoselective Polymerization of Conjugated Dienes and Styrene−Butadiene Copolymerization Promoted by Octahedral Titanium Catalyst

The ability of the dichloro{1,4-dithiabutanediyl-2,2‘-bis(4,6-di-tert-butylphenoxy)}titanium complex (1) to catalyze homopolymerization of conjugated dienes and copolymerization of butadiene with styrene is reported. After proper activation with methylalumoxane, 1 resulted active in the trans-1,4 se...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Macromolecules 2007-08, Vol.40 (16), p.5638-5643
Hauptverfasser:	Milione, Stefano, Cuomo, Cinzia, Capacchione, Carmine, Zannoni, Carla, Grassi, Alfonso, Proto, Antonio
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!