Hierarchical Amplification of Macromolecular Helicity in a Lyotropic Liquid Crystalline Charged Poly(phenylacetylene) by Nonracemic Dopants in Water and Its Helical Structure

We report a unique hierarchical amplification of chiral information from a nonracemic guest to macromolecular helicity, followed by a mesoscopic, supramolecular cholesteric twist in water. This remarkable chiral amplification involves two-step chirality transfer processes, which enable the detection...

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Veröffentlicht in:	Macromolecules 2006-08, Vol.39 (16), p.5371-5380
Hauptverfasser:	Nagai, Kanji, Sakajiri, Koichi, Maeda, Katsuhiro, Okoshi, Kento, Sato, Takahiro, Yashima, Eiji
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Solution and gel properties
Online-Zugang:	Volltext
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