Thiol−Vinyl Mechanisms. 1. Termination and Propagation Kinetics in Thiol−Ene Photopolymerizations

In this work, termination and propagation kinetics of thiol−ene photopolymerizations are investigated via unsteady-state analysis, and termination is shown to occur though bimolecular radical−radical recombinations. The termination rate is too rapid to be resolved by standard differential scanning c...

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Veröffentlicht in:	Macromolecules 2006-05, Vol.39 (10), p.3673-3680
Hauptverfasser:	Reddy, Sirish K, Cramer, Neil B, Bowman, Christopher N
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Physicochemistry of polymers Polymerization Polymers and radiations
Online-Zugang:	Volltext
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