Nitroxide-Mediated Controlled Free-Radical Emulsion Polymerization Using a Difunctional Water-Soluble Alkoxyamine Initiator. Toward the Control of Particle Size, Particle Size Distribution, and the Synthesis of Triblock Copolymers

A novel dialkoxyamine bearing two carboxylic acid groups was synthesized by the addition of a high dissociation rate constant alkoxyamine onto tri(ethylene glycol) diacrylate. This dialkoxyamine was first successfully used as an initiator for the bulk polymerizations of n-butyl acrylate and styrene....

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Veröffentlicht in:	Macromolecules 2005-11, Vol.38 (24), p.9963-9973
Hauptverfasser:	Nicolas, Julien, Charleux, Bernadette, Guerret, Olivier, Magnet, Stéphanie
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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