Thermal Atropisomerization and Photoluminiscence Spectra of Very High Glass Transition Temperature Chiral Poly(binaphthoxyphosphazenes) with a Secondary Helicoidal Structure

The optically active ([α] = −192°) and mesomorphic (2θ = 6°, d = 14.7 Å) isotactic poly(2,2‘-dioxy-1,1‘-binaphthylphosphazene) R-(−)-[NP(O2C20H12)] n (1-R) (M w = 840 000) has a very high glass transition temperature, T g (329 °C), and can be thermally degraded between 100 and 160 °C to lower M w di...

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Veröffentlicht in:	Macromolecules 2004-07, Vol.37 (14), p.5437-5443
Hauptverfasser:	Carriedo, Gabino A, Álvarez, J. Luis García, García Alonso, F. J, Soto, A. Presa, Tarazona, M. Pilar, Mendicuti, Francisco, Marcelo, Gema
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Inorganic and organomineral polymers Physicochemistry of polymers Properties and characterization
Online-Zugang:	Volltext
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