Hierarchical Self-Organization of ABC Terpolymer Constituted of a Long Polyelectrolyte End-Capped by Different Hydrophobic Blocks
The self-organization of a mono hydrophilic ABC terpolymer, which is constituted of a central long polyelectrolyte end-capped by two different hydrophobic short blocks (i.e., polystyrene-b-poly(acrylic acid)-b-poly(n-butyl methacrylate), PS−PAA−PnBMA), was examined in aqueous salt-free dilute soluti...
Gespeichert in:
| Veröffentlicht in: | Macromolecules 2005-02, Vol.38 (4), p.1307-1314 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1314 |
|---|---|
| container_issue | 4 |
| container_start_page | 1307 |
| container_title | Macromolecules |
| container_volume | 38 |
| creator | Katsampas, Ilias Tsitsilianis, Constantinos |
| description | The self-organization of a mono hydrophilic ABC terpolymer, which is constituted of a central long polyelectrolyte end-capped by two different hydrophobic short blocks (i.e., polystyrene-b-poly(acrylic acid)-b-poly(n-butyl methacrylate), PS−PAA−PnBMA), was examined in aqueous salt-free dilute solutions by static and dynamic light scattering, scanning electron microscopy, and rheology. The neutralized PS−PAA−PnBMA terpolymer is self-organized hierarchically from flowerlike micelles to dendronlike micellar aggregates and eventually to a three-dimensional physical network. The rheological properties of the resulting physical gel were also investigated and discussed. |
| doi_str_mv | 10.1021/ma048275c |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_ma048275c</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d176208363</sourcerecordid><originalsourceid>FETCH-LOGICAL-a289t-f82c3d723d723a3a8a7e39fd602b3be07d4cd7f482cae451d3e59f794f0050f83</originalsourceid><addsrcrecordid>eNptkD9PwzAQxS0EEqUw8A28MDAE_CdukrENhSJVKhJljq6O3bqkdmSbIWx8c1KK6MJwupPe7570HkLXlNxRwuj9Dkias0zIEzSggpFE5FycogEhLE0KVmTn6CKELSGUipQP0NfMKA9eboyEBr-qRicLvwZrPiEaZ7HTeDwp8VL51jXdTnlcOhuiiR9R1XsV8NzZNX7pVdUoGX1_RIWntk5KaNseWnX4wWitvLIRz7rau3bjVkbiSePke7hEZxqaoK5-9xC9PU6X5SyZL56ey_E8AZYXMdE5k7zO2M8AhxwyxQtdjwhb8ZUiWZ3KOtN9eAkqFbTmShQ6K1JNiCA650N0e_CV3oXgla5ab3bgu4qSat9d9dddz94c2BZC34v2YKUJx4eR4GLEyZEDGaqt-_C2T_CP3zdlRXw4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Hierarchical Self-Organization of ABC Terpolymer Constituted of a Long Polyelectrolyte End-Capped by Different Hydrophobic Blocks</title><source>ACS Publications</source><creator>Katsampas, Ilias ; Tsitsilianis, Constantinos</creator><creatorcontrib>Katsampas, Ilias ; Tsitsilianis, Constantinos</creatorcontrib><description>The self-organization of a mono hydrophilic ABC terpolymer, which is constituted of a central long polyelectrolyte end-capped by two different hydrophobic short blocks (i.e., polystyrene-b-poly(acrylic acid)-b-poly(n-butyl methacrylate), PS−PAA−PnBMA), was examined in aqueous salt-free dilute solutions by static and dynamic light scattering, scanning electron microscopy, and rheology. The neutralized PS−PAA−PnBMA terpolymer is self-organized hierarchically from flowerlike micelles to dendronlike micellar aggregates and eventually to a three-dimensional physical network. The rheological properties of the resulting physical gel were also investigated and discussed.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma048275c</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Solution and gel properties</subject><ispartof>Macromolecules, 2005-02, Vol.38 (4), p.1307-1314</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a289t-f82c3d723d723a3a8a7e39fd602b3be07d4cd7f482cae451d3e59f794f0050f83</citedby><cites>FETCH-LOGICAL-a289t-f82c3d723d723a3a8a7e39fd602b3be07d4cd7f482cae451d3e59f794f0050f83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ma048275c$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ma048275c$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16535630$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Katsampas, Ilias</creatorcontrib><creatorcontrib>Tsitsilianis, Constantinos</creatorcontrib><title>Hierarchical Self-Organization of ABC Terpolymer Constituted of a Long Polyelectrolyte End-Capped by Different Hydrophobic Blocks</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>The self-organization of a mono hydrophilic ABC terpolymer, which is constituted of a central long polyelectrolyte end-capped by two different hydrophobic short blocks (i.e., polystyrene-b-poly(acrylic acid)-b-poly(n-butyl methacrylate), PS−PAA−PnBMA), was examined in aqueous salt-free dilute solutions by static and dynamic light scattering, scanning electron microscopy, and rheology. The neutralized PS−PAA−PnBMA terpolymer is self-organized hierarchically from flowerlike micelles to dendronlike micellar aggregates and eventually to a three-dimensional physical network. The rheological properties of the resulting physical gel were also investigated and discussed.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Solution and gel properties</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkD9PwzAQxS0EEqUw8A28MDAE_CdukrENhSJVKhJljq6O3bqkdmSbIWx8c1KK6MJwupPe7570HkLXlNxRwuj9Dkias0zIEzSggpFE5FycogEhLE0KVmTn6CKELSGUipQP0NfMKA9eboyEBr-qRicLvwZrPiEaZ7HTeDwp8VL51jXdTnlcOhuiiR9R1XsV8NzZNX7pVdUoGX1_RIWntk5KaNseWnX4wWitvLIRz7rau3bjVkbiSePke7hEZxqaoK5-9xC9PU6X5SyZL56ey_E8AZYXMdE5k7zO2M8AhxwyxQtdjwhb8ZUiWZ3KOtN9eAkqFbTmShQ6K1JNiCA650N0e_CV3oXgla5ab3bgu4qSat9d9dddz94c2BZC34v2YKUJx4eR4GLEyZEDGaqt-_C2T_CP3zdlRXw4</recordid><startdate>20050222</startdate><enddate>20050222</enddate><creator>Katsampas, Ilias</creator><creator>Tsitsilianis, Constantinos</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050222</creationdate><title>Hierarchical Self-Organization of ABC Terpolymer Constituted of a Long Polyelectrolyte End-Capped by Different Hydrophobic Blocks</title><author>Katsampas, Ilias ; Tsitsilianis, Constantinos</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a289t-f82c3d723d723a3a8a7e39fd602b3be07d4cd7f482cae451d3e59f794f0050f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Solution and gel properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Katsampas, Ilias</creatorcontrib><creatorcontrib>Tsitsilianis, Constantinos</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Katsampas, Ilias</au><au>Tsitsilianis, Constantinos</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hierarchical Self-Organization of ABC Terpolymer Constituted of a Long Polyelectrolyte End-Capped by Different Hydrophobic Blocks</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2005-02-22</date><risdate>2005</risdate><volume>38</volume><issue>4</issue><spage>1307</spage><epage>1314</epage><pages>1307-1314</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>The self-organization of a mono hydrophilic ABC terpolymer, which is constituted of a central long polyelectrolyte end-capped by two different hydrophobic short blocks (i.e., polystyrene-b-poly(acrylic acid)-b-poly(n-butyl methacrylate), PS−PAA−PnBMA), was examined in aqueous salt-free dilute solutions by static and dynamic light scattering, scanning electron microscopy, and rheology. The neutralized PS−PAA−PnBMA terpolymer is self-organized hierarchically from flowerlike micelles to dendronlike micellar aggregates and eventually to a three-dimensional physical network. The rheological properties of the resulting physical gel were also investigated and discussed.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma048275c</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0024-9297 |
| ispartof | Macromolecules, 2005-02, Vol.38 (4), p.1307-1314 |
| issn | 0024-9297 1520-5835 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ma048275c |
| source | ACS Publications |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Solution and gel properties |
| title | Hierarchical Self-Organization of ABC Terpolymer Constituted of a Long Polyelectrolyte End-Capped by Different Hydrophobic Blocks |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T08%3A22%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hierarchical%20Self-Organization%20of%20ABC%20Terpolymer%20Constituted%20of%20a%20Long%20Polyelectrolyte%20End-Capped%20by%20Different%20Hydrophobic%20Blocks&rft.jtitle=Macromolecules&rft.au=Katsampas,%20Ilias&rft.date=2005-02-22&rft.volume=38&rft.issue=4&rft.spage=1307&rft.epage=1314&rft.pages=1307-1314&rft.issn=0024-9297&rft.eissn=1520-5835&rft.coden=MAMOBX&rft_id=info:doi/10.1021/ma048275c&rft_dat=%3Cacs_cross%3Ed176208363%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |