Copolymerization of Tetrafluoroethylene and 2,2-Bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole in Supercritical Carbon Dioxide

Copolymers of tetrafluoroethylene (TFE) and 2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole (PDD) were synthesized in carbon dioxide at low temperatures. Bis(perfluoro-2-N-propoxypropionyl) peroxide was used as initiator. A range of copolymers with various compositions and different molecular weig...

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Veröffentlicht in:	Macromolecules 2003-09, Vol.36 (19), p.7107-7113
Hauptverfasser:	Michel, U, Resnick, P, Kipp, B, DeSimone, J. M
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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