Influence of Cocatalyst on the Stereoselectivity of Unbridged 2-Phenylindenyl Metallocene Catalysts

Unbridged 2-arylindenyl metallocene complexes, such as bis(2-phenylindenyl)zirconium dichloride, in the presence of methylaluminoxane (MAO), are catalyst precursors for the synthesis of elastomeric polypropylene. The nature of the cocatalyst is shown to have a significant influence on the productivi...

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Veröffentlicht in:	Macromolecules 2002-08, Vol.35 (18), p.6766-6772
Hauptverfasser:	Wilmes, Gregg M, Polse, Jennifer L, Waymouth, Robert M
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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