Controlled/“Living” Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate

Controlled/“Living” Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate

ATRP of the first cyclic olefin, methyl 1-cyclobutenecarboxylate (MCBE), by addition polymerization in a well controlled/“living” manner is described, along with a new practical method to synthesize MCBE. The polydispersity of poly(methyl 1-cyclobutenecarboxylate) (PMCBE) synthesized by a convention...

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Veröffentlicht in:Macromolecules 2002-05, Vol.35 (11), p.4277-4281
Hauptverfasser: Chen, Xiao-Ping, Sufi, Bilal A, Padias, Anne Buyle, Hall, H. K
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Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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container_end_page 4281
container_issue 11
container_start_page 4277
container_title Macromolecules
container_volume 35
creator Chen, Xiao-Ping
Sufi, Bilal A
Padias, Anne Buyle
Hall, H. K
description ATRP of the first cyclic olefin, methyl 1-cyclobutenecarboxylate (MCBE), by addition polymerization in a well controlled/“living” manner is described, along with a new practical method to synthesize MCBE. The polydispersity of poly(methyl 1-cyclobutenecarboxylate) (PMCBE) synthesized by a conventional ATRP initiation system was narrow (M w/M n = 1.1−1.4), but M n was usually less than half of the theoretical number-average molecular weight. However, the polymerization of MCBE initiated by a reverse ATRP initiation system, AIBN/CuBr2/dNbpy, was well controlled; the rate of polymerization was first order in monomer, and the molecular weights of the polymers were close to the designed values with very narrow polydispersities (M w/M n = ∼1.15). The obtained polymer PMCBE can be used as a macroinitiator to further polymerize a second monomer, such as styrene.
doi_str_mv 10.1021/ma012104f
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Controlled/“Living” Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate
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