Thermodynamics of Ionic Surfactant Adsorption with Account for the Counterion Binding:  Effect of Salts of Various Valency

The effect of counterion binding on the surface tension and surface potential of ionic surfactant solutions is accounted for theoretically. It turns out that no every couple of surfactant and counterion adsorption isotherms are thermodynamically compatible. To solve the problem, we develop a formali...

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Veröffentlicht in:	Langmuir 1999-03, Vol.15 (7), p.2351-2365
Hauptverfasser:	Kralchevsky, P. A, Danov, K. D, Broze, G, Mehreteab, A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Surface physical chemistry Surface-active agents: properties
Online-Zugang:	Volltext
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