Equilibrium and Saturation Coverage Studies of Alkyl and Aryl Isocyanides on Powdered Gold

Isocyanides (C=-N-R) adsorbed from 1,2-dichloroethane(DCE) solution on powdered gold were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Concentration measurements showed that adsorption equilibrium constants decrease in the order: CNPh > CNCH{sub 2}C(O)OEt >...

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Veröffentlicht in:	Langmuir 1995-07, Vol.11 (7), p.2539-2546
Hauptverfasser:	Shih, Kuo-Chen, Angelici, Robert J
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY ABUNDANCE ADSORPTION ALKYL RADICALS ARYL RADICALS Chemistry CYANIDES Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry GOLD INFRARED SPECTRA Solid-liquid interface Surface physical chemistry
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