Infrared and ab Initio Study of the Chloride−Ammonia Anion Complex

The infrared spectrum of the Cl-−NH3 anion complex has been recorded in the 2900−3450 cm-1 range by monitoring the infrared-induced production of Cl- anion fragments in a tandem mass spectrometer. The spectrum features an intense band centered at 3140 cm-1, which is shifted by 196 cm-1 to lower freq...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2000-03, Vol.104 (12), p.2562-2566
Hauptverfasser: Weiser, P. S, Wild, D. A, Wolynec, P. P, Bieske, E. J
Format: Artikel
Sprache:eng
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