Laser Photolysis Studies on Photodissociation of Axial Ligands from Isocyanide Complexes of Cobalt(III) and Rhodium(III) Porphyrins in Toluene Solutions. A Comparison with the Photochemistry of Carbonylrhodium(III) Porphyrin

Chlorocobalt(III) and iodorhodium(III) tetraphenylporphyrins, (Cl)CoIIITPP and (I)RhIIITPP, react with 2,6-dimethylphenyl isocyanide (R−NC) in toluene solutions to give the isocyanide complexes, (Cl)(R−NC)CoIIITPP and (I)(R−NC)RhIIITPP, respectively. The 355-nm laser photolysis studies have shown th...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1999-05, Vol.103 (19), p.3672-3677
Hauptverfasser:	Hoshino, Mikio, Nagamori, Takahiro, Seki, Hiroshi, Tase, Takahiro, Chihara, Teiji, Lillis, Jerome P, Wakatsuki, Yasuhiro
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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