Aggregation Quenching of Luminescence in Electroluminescent Conjugated Polymers
We report measurements of photoluminescence from films of a soluble phenylenevinylene polymer that has prospective importance as the emissive material in light-emitting diodes. We show unambiguously that there is long-lived emission in this material due to excimers and estimate that the quantum yiel...
Gespeichert in:
| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1999-04, Vol.103 (14), p.2394-2398 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2398 |
|---|---|
| container_issue | 14 |
| container_start_page | 2394 |
| container_title | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
| container_volume | 103 |
| creator | Jakubiak, Rachel Collison, Christopher J Wan, Wai Chou Rothberg, Lewis J Hsieh, Bing R |
| description | We report measurements of photoluminescence from films of a soluble phenylenevinylene polymer that has prospective importance as the emissive material in light-emitting diodes. We show unambiguously that there is long-lived emission in this material due to excimers and estimate that the quantum yield for excimer formation is as high as 50%. Since excimers in this polymer largely decay nonradiatively at ambient temperature, their prominence serves to drastically reduce the possible efficiency of electroluminescent conjugated polymer devices. |
| doi_str_mv | 10.1021/jp9839450 |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_jp9839450</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d257060270</sourcerecordid><originalsourceid>FETCH-LOGICAL-a361t-79d05890ae07837cefad8cd295e91c3bf178a9eb863ebdc224e61ad8a8751cba3</originalsourceid><addsrcrecordid>eNptkD9PwzAUxC0EEqUw8A2yMDAE_KeO7bFEbUGq1AKF1XKcl5CQxpWdSO23J6ioE9M9nX7vpDuEbgl-IJiSx3qnJFMTjs_QiHCKY04JPx9uLFXME6Yu0VUINcaYMDoZodW0LD2UpqtcG7320Nqvqi0jV0TLflu1EOxgQVS10awB23nXnOwuSl1b98Mv5NHaNYct-HCNLgrTBLj50zH6mM826XO8XC1e0ukyNiwhXSxUjrlU2AAWkgkLhcmlzanioIhlWUGENAoymTDIckvpBBIyIEYKTmxm2BjdH3OtdyF4KPTOV1vjD5pg_buEPi0xsPGRrUIH-xNo_LdOBBNcb9bv-o0-pXxOFvpz4O-OvLFB16737dDkn9wfxxNtUw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Aggregation Quenching of Luminescence in Electroluminescent Conjugated Polymers</title><source>ACS Journals: American Chemical Society Web Editions</source><creator>Jakubiak, Rachel ; Collison, Christopher J ; Wan, Wai Chou ; Rothberg, Lewis J ; Hsieh, Bing R</creator><creatorcontrib>Jakubiak, Rachel ; Collison, Christopher J ; Wan, Wai Chou ; Rothberg, Lewis J ; Hsieh, Bing R</creatorcontrib><description>We report measurements of photoluminescence from films of a soluble phenylenevinylene polymer that has prospective importance as the emissive material in light-emitting diodes. We show unambiguously that there is long-lived emission in this material due to excimers and estimate that the quantum yield for excimer formation is as high as 50%. Since excimers in this polymer largely decay nonradiatively at ambient temperature, their prominence serves to drastically reduce the possible efficiency of electroluminescent conjugated polymer devices.</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/jp9839450</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 1999-04, Vol.103 (14), p.2394-2398</ispartof><rights>Copyright © 1999 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-79d05890ae07837cefad8cd295e91c3bf178a9eb863ebdc224e61ad8a8751cba3</citedby><cites>FETCH-LOGICAL-a361t-79d05890ae07837cefad8cd295e91c3bf178a9eb863ebdc224e61ad8a8751cba3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp9839450$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp9839450$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27075,27923,27924,56737,56787</link.rule.ids></links><search><creatorcontrib>Jakubiak, Rachel</creatorcontrib><creatorcontrib>Collison, Christopher J</creatorcontrib><creatorcontrib>Wan, Wai Chou</creatorcontrib><creatorcontrib>Rothberg, Lewis J</creatorcontrib><creatorcontrib>Hsieh, Bing R</creatorcontrib><title>Aggregation Quenching of Luminescence in Electroluminescent Conjugated Polymers</title><title>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</title><addtitle>J. Phys. Chem. A</addtitle><description>We report measurements of photoluminescence from films of a soluble phenylenevinylene polymer that has prospective importance as the emissive material in light-emitting diodes. We show unambiguously that there is long-lived emission in this material due to excimers and estimate that the quantum yield for excimer formation is as high as 50%. Since excimers in this polymer largely decay nonradiatively at ambient temperature, their prominence serves to drastically reduce the possible efficiency of electroluminescent conjugated polymer devices.</description><issn>1089-5639</issn><issn>1520-5215</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNptkD9PwzAUxC0EEqUw8A2yMDAE_KeO7bFEbUGq1AKF1XKcl5CQxpWdSO23J6ioE9M9nX7vpDuEbgl-IJiSx3qnJFMTjs_QiHCKY04JPx9uLFXME6Yu0VUINcaYMDoZodW0LD2UpqtcG7320Nqvqi0jV0TLflu1EOxgQVS10awB23nXnOwuSl1b98Mv5NHaNYct-HCNLgrTBLj50zH6mM826XO8XC1e0ukyNiwhXSxUjrlU2AAWkgkLhcmlzanioIhlWUGENAoymTDIckvpBBIyIEYKTmxm2BjdH3OtdyF4KPTOV1vjD5pg_buEPi0xsPGRrUIH-xNo_LdOBBNcb9bv-o0-pXxOFvpz4O-OvLFB16737dDkn9wfxxNtUw</recordid><startdate>19990408</startdate><enddate>19990408</enddate><creator>Jakubiak, Rachel</creator><creator>Collison, Christopher J</creator><creator>Wan, Wai Chou</creator><creator>Rothberg, Lewis J</creator><creator>Hsieh, Bing R</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19990408</creationdate><title>Aggregation Quenching of Luminescence in Electroluminescent Conjugated Polymers</title><author>Jakubiak, Rachel ; Collison, Christopher J ; Wan, Wai Chou ; Rothberg, Lewis J ; Hsieh, Bing R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-79d05890ae07837cefad8cd295e91c3bf178a9eb863ebdc224e61ad8a8751cba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jakubiak, Rachel</creatorcontrib><creatorcontrib>Collison, Christopher J</creatorcontrib><creatorcontrib>Wan, Wai Chou</creatorcontrib><creatorcontrib>Rothberg, Lewis J</creatorcontrib><creatorcontrib>Hsieh, Bing R</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jakubiak, Rachel</au><au>Collison, Christopher J</au><au>Wan, Wai Chou</au><au>Rothberg, Lewis J</au><au>Hsieh, Bing R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aggregation Quenching of Luminescence in Electroluminescent Conjugated Polymers</atitle><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</jtitle><addtitle>J. Phys. Chem. A</addtitle><date>1999-04-08</date><risdate>1999</risdate><volume>103</volume><issue>14</issue><spage>2394</spage><epage>2398</epage><pages>2394-2398</pages><issn>1089-5639</issn><eissn>1520-5215</eissn><abstract>We report measurements of photoluminescence from films of a soluble phenylenevinylene polymer that has prospective importance as the emissive material in light-emitting diodes. We show unambiguously that there is long-lived emission in this material due to excimers and estimate that the quantum yield for excimer formation is as high as 50%. Since excimers in this polymer largely decay nonradiatively at ambient temperature, their prominence serves to drastically reduce the possible efficiency of electroluminescent conjugated polymer devices.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp9839450</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1089-5639 |
| ispartof | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 1999-04, Vol.103 (14), p.2394-2398 |
| issn | 1089-5639 1520-5215 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_jp9839450 |
| source | ACS Journals: American Chemical Society Web Editions |
| title | Aggregation Quenching of Luminescence in Electroluminescent Conjugated Polymers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T20%3A02%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Aggregation%20Quenching%20of%20Luminescence%20in%20Electroluminescent%20Conjugated%20Polymers&rft.jtitle=The%20journal%20of%20physical%20chemistry.%20A,%20Molecules,%20spectroscopy,%20kinetics,%20environment,%20&%20general%20theory&rft.au=Jakubiak,%20Rachel&rft.date=1999-04-08&rft.volume=103&rft.issue=14&rft.spage=2394&rft.epage=2398&rft.pages=2394-2398&rft.issn=1089-5639&rft.eissn=1520-5215&rft_id=info:doi/10.1021/jp9839450&rft_dat=%3Cacs_cross%3Ed257060270%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |